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2024年12月27日 星期五

日本的遠古岩石揭露了關於海洋缺氧事件的線索

 原文網址:https://news.northwestern.edu/stories/2024/12/prehistoric-rock-in-japan-reveals-clues-to-major-ocean-anoxic-event/

By Amanda Morris

在研究日本盧別岳一帶出露的遠古岩石與化石之後,研究人員對於海洋缺氧事件1a(OAE 1a)的發生年代與持續時間重新得到了更加精準的數值。這場極為嚴重的環境惡化事件使得地球海洋無法吸到氧氣,造成大量生物滅絕,又以浮游生物受到的打擊特別嚴重。

在新研究當中,研究人員探討的對象並非深海,而是日本北海道盧別岳的西北側露出的古代岩層。這些稱為凝灰岩的岩石是由經年累月堆積下來的火山灰固結而成。圖片來源:Luca Podrecca

2023年9月4日 星期一

加強化學風化是解決氣候危機的方法之一?

 原文網址:https://press.uni-mainz.de/enhanced-chemical-weathering-a-solution-to-the-climate-crisis/

地球正在不斷變熱——今年全球的夏季也明顯看到這會有什麼樣的後果。但回顧地質歷史,全球暖化事件並不罕見:距今大約5600萬年前稱作古新世─始新世氣候最暖期(Paleocene–Eocene Thermal Maximum ,PETM)的時代,地球的平均氣溫上升了5-8度。氣候會如此發展最有可能的原因是火山活動增加,連帶造成許多二氧化碳釋放到大氣當中。這股高溫持續了大約20萬年左右。回到2021年,約翰尼斯・古騰堡-美茵茲大學的教授Philip Pogge von Strandmann探討了最後是什麼樣的效應結束了PETM暖化事件,使得全球氣溫降低而讓氣候回復到原狀。結果簡單來說,是雨水跟大氣中的二氧化碳結合成碳酸,使得岩石風化速度提高而把鈣鎂釋放出來。接著河川把這些鈣、鎂、碳酸帶到海洋,在此鈣、鎂以及碳酸(亦即二氧化碳)結合成不可溶的石灰岩。「換句話說,自然界有道回饋作用可以幫助調控氣候。高溫可以加速岩石的化學風化過程,使得大氣中的二氧化碳含量降低,讓氣候得以回復原狀,」Pogge von Strandmann表示。

從d7Li的數據和模擬結果推測地球系統可能的變化過程。圖片來源:自然—地球科學

2020年3月17日 星期二

延誤送達!水、碳、氮並沒有在一開始就供應給地球


延誤送達!水、碳、氮並沒有在一開始就供應給地球
在發表於《自然》(Nature)的論文中,科隆大學的科學家對地球生命和海洋的起源有了重大的新發現。他們測量保存在格陵蘭最古老的地函岩石之後,顯示出跟過往的假設相反,生命演化必需的元素要在地球幾乎完全成形時才抵達地球。
出露在格陵蘭西南部地表,年代有38億年的地函岩石。圖片來源:Kristoffer Szilas

2019年5月10日 星期五

早期動物演化過程中的興衰更迭與氧氣大有關係


早期動物演化過程中的興衰更迭與氧氣大有關係
複雜動物迅速演化的關鍵時期大約始於5.4億年前。新的研究發現了和這段時期有關的重要線索。

2018年3月2日 星期五

於近代發生的火山活動跟地球誕生之後不久的事件有所關聯


原文網址:https://carnegiescience.edu/news/modern-volcanism-tied-events-occurring-soon-after-earth%E2%80%99s-birth
於近代發生的火山活動跟地球誕生之後不久的事件有所關聯
印度洋上的留尼旺島是由火山熱點形成。根據卡內基科學研究所的Bradley Peters、Richard Carlson、Mary Horan,以及斯克里普斯海洋研究所的James Day發表在《自然》(Nature)的新成果,此熱點的高溫岩漿柱是從地下深處成分異常原始的地方湧升而成。
留尼旺島標示出一處曾在6600萬年前噴發的熱點當今的所在位置。該次噴發產生的洪流玄武岩形成了覆蓋印度大部分地區的德干高原,而恐龍的滅絕它可能也參與了一部分。相較於地表多數火山,一般認為洪流玄武岩和其他熱點產生的岩漿係源自於地球深部的不同位置。因此研究這些物質或許可以幫助科學家更加瞭解我們居住的地球是如何演變。
地球形成過程中的高熱使得當時的地球處於大規模的熔融狀態,造成地球分離成兩層――密度高的金屬往內沉至核心位置形成地核,留下浮於上方富含矽酸鹽的地函。
在地球接下來45億年的演變過程中,地函深部上湧、熔化,然後再次因為密度而分離,形成地殼並在整個過程中改變地球內部的化學成分。今日,地殼正沿著太平洋的邊界沉回地球內部,此種現象會讓地函緩緩流動而攪動這些物質,使得地殼特有的化學成分重新回到地球深處。
但是,地函並非全都如此過程所述的經過充分混和。有些年代較老的區塊至今仍然存在――就像未經充分攪拌的蛋糕麵糊中出現的麵粉團塊一樣。分析留尼旺島火山岩的化學成分,顯示它們的來源不同於地函今日其他混和良好的地方。
研究團隊利用新的同位素數據,顯示產生留尼旺島岩漿的區域是獨立於範圍較廣、充分混和的地函之外。這些獨立存在的區塊形成的時間早於地球歷史的最初十分之一。
同位素是一群質子數量相同,但是中子數量卻不同的元素。有時原子核含有的中子數量會讓同位素呈現不穩定的狀態。為了變成穩定狀態,這類同位素會經由放射性衰變的過程來釋放出帶有能量的粒子。同位素的質子和中子數量在過程中會有所變化,使它們轉變成另一種元素。這項新研究利用此種作用留下的線索來得到這些特殊地函區塊的年代以及歷史。
釤-146就是一種不穩定的(即「放射性」)同位素,它會衰變成釹-142,半衰期僅有1.03億年。雖然地球剛形成時帶有釤-146,但它很快地就會在地球的幼年期消失殆盡。這意謂釹-142可以詳細紀錄地球最早期的歷史,卻不會記下釤-146通通轉變成釹-142之後的地球歷史。在地球45億年的歷史當中,只有最初5億年在地函發生的成分變化,才會造成釹-142跟其他釹同位素含量的比例出現差異。
分析留尼旺島火山岩中釹-142跟釹-144的比例,配合在實驗室進行的模擬研究,指出地函的混和作用儘管已經進行數十億年之久,留尼旺島地函柱的岩漿可能是來自於地函一處保存良好的區塊,曾經歷地函最初發生的大規模熔融作用使成分有所改變。
研究團隊的發現也有助於科學家解釋正好位在地核和地核邊界的高密度區域起源為何。這類區域稱為大型低剪力波速群(large low shear velocity provinces, LLSVP)與超低速帶(ultralow velocity zones ,ULVZ),當地震波經過深部地函的這些區域時波速通常會下降。它們也許是地球早期的熔融事件殘留下來的痕跡。
主要作者Peters表示:「這些熱點地函柱中保留下來的地函分化事件,可以讓我們更加瞭解早期地球的地球化學作用,並且解釋那些位在地函深處的高密度區域產生的謎樣地震波訊號。」

Modern volcanism tied to events occurring soon after earth’s birth
Plumes of hot magma from the volcanic hotspot that formed Réunion Island in the Indian Ocean rise from an unusually primitive source deep beneath the Earth’s surface, according to new work in Nature from Carnegie’s Bradley Peters, Richard Carlson, and Mary Horan along with James Day of the Scripps Institution of Oceanography.
Réunion marks the present-day location of the hotspot that 66 million years ago erupted the Deccan Traps flood basalts, which cover most of India and may have contributed to the extinction of the dinosaurs. Flood basalts and other hotspot lavas are thought to originate from different portions of Earth’s deep interior than most volcanoes at Earth’s surface and studying this material may help scientists understand our home planet’s evolution.
The heat from Earth’s formation process caused extensive melting of the planet, leading Earth to separate into two layers when the denser iron metal sank inward toward the center, creating the core and leaving the silicate-rich mantle floating above. 
Over the subsequent 4.5 billion years of Earth’s evolution, deep portions of the mantle would rise upwards, melt, and then separate once again by density, creating Earth’s crust and changing the chemical composition of Earth’s interior in the process.  As crust sinks back into Earth’s interior—a phenomenon that’s occurring today along the boundary of the Pacific Ocean—the slow motion of Earth’s mantle works to stir these materials, along with their distinct chemistry, back into the deep Earth.
But not all of the mantle is as well-blended as this process would indicate. Some older patches still exist—like powdery pockets in a poorly mixed bowl of cake batter. Analysis of the chemical compositions of Réunion Island volcanic rocks indicate that their source material is different from other, better-mixed parts of the modern mantle.
Using new isotope data, the research team revealed that Réunion lavas originate from regions of the mantle that were isolated from the broader, well-blended mantle. These isolated pockets were formed within the first ten percent of Earth’s history.
Isotopes are elements that have the same number of protons, but a different number of neutrons. Sometimes, the number of neutrons present in the nucleus make an isotope unstable; to gain stability, the isotope will release energetic particles in the process of radioactive decay. This process alters its number of protons and neutrons and transforms it into a different element. This new study harnesses this process to provide a fingerprint for the age and history of distinct mantle pockets.
Samarium-146 is one such unstable, or radioactive, isotope with a half-life of only 103 million years. It decays to the isotope neodymium-142. Although samarium-146 was present when Earth formed, it became extinct very early in Earth’s infancy, meaning neodymium-142 provides a good record of Earth’s earliest history, but no record of the Earth from the period after all the samarium-146 transformed into neodymium-142. Differences in the abundances of neodymium-142 in comparison to other isotopes of neodymium could only have been generated by changes in the chemical composition of the mantle that occurred in the first 500 million years of Earth’s 4.5 billion-year history.
The ratio of neodymium-142 to neodymium-144 in Réunion volcanic rocks, together with the results of lab-based mimicry and modeling studies, indicate that despite billions of years of mantle mixing, Réunion plume magma likely originates from a preserved pocket of the mantle that experienced a compositional change caused by large-scale melting of the Earth’s earliest mantle.
The team’s findings could also help explain the origin of dense regions right at the boundary of the core and mantle called large low shear velocity provinces (LLSVPs) and ultralow velocity zones (ULVZs), reflecting the unusually slow speed of seismic waves as they travel through these regions of the deep mantle. Such regions may be relics of early melting events.
“The mantle differentiation event preserved in these hotspot plumes can both teach us about early Earth geochemical processes and explain the mysterious seismic signatures created by these dense deep-mantle zones,” said lead author Peters.
原始論文:Bradley J. Peters, Richard W. Carlson, James M. D. Day, Mary F. Horan. Hadean silicate differentiation preserved by anomalous 142Nd/144Nd ratios in the Réunion hotspot source. Nature, 2018; 555 (7694): 89 DOI: 10.1038/nature25754
引用自:Carnegie Institution for Science. "Modern volcanism tied to events occurring soon after Earth's birth: Primordial mantle pockets preserved under Réunion Island for billions of years." 

2018年1月25日 星期四

在一團混亂中分離的地核和地函

在一團混亂中分離的地核和地函
根據卡內基研究院和史密森尼學會的科學家團隊發表在《自然》(Nature)的新研究,從地函內部湧升至火山熱點的岩石熱柱所含有的證據顯示,地球形成時的那段歲月可能比我們之前認為的還要混亂許多。
科學家已經清楚知道地球是由環繞幼年太陽的物質加積而成。當地球最後成長至足夠大小時密度較高的鐵沉入地球內部而形成地核的原型,剩下富含矽酸鹽的地函漂在上方。
但卡內基研究院的Yingwei Fei,以及同時隸屬於卡內基研究院和史密森尼學會的Colin Jackson領導的團隊進行的新研究,卻主張地函和地核的分離過程並非很有秩序地進行。
「我們的發現指出雖然地核是從地函分離出來,但地函本身從來沒有完整混合過。」Jackson解釋,「這令人感到十分驚訝。在地球的成長過程中,經歷了早期太陽系的其他天體重重撞擊之後緊接著形成了地核。這些撞擊事件跟之後形成月球的超大撞擊事件頗為相似。過去,科學家大都認為這些撞擊事件產生的巨大能量可以徹底翻攪地函,使得地函成分被攪拌得相當均一。」
讓團隊得出他們假設的關鍵證據來自於夏威夷之類的火山熱點,他們在此找到了獨特且古老的鎢和氙同位素訊號。雖然一般相信地函柱是來自於地函最深的區域,但這些特殊的同位素訊號起源為何仍有很大的爭議。研究團隊認為答案就在氙的母元素――碘――在非常高的壓力之下的化學性質。
同位素是同一元素質子數相同但中子數不同的版本。元素的放射性同位素是不穩定的,比方說碘-129。為了變成穩定狀態,碘-129會衰變成氙-129。因此,在地函柱樣品中的氙同位素訊號和碘在地核跟地函分離時的行為有直接關聯。
Jackson、Fei和共同作者――卡內基研究院的Neil Bennett和Zhixue Du,以及史密森尼學會的Elizabeth Cottrell,利用鑽石高壓砧來重現地球的地核從地函分離時的極端環境,來測量碘在當時如何分散至金屬地核和矽酸鹽質地函。他們也證實了如果地函還在成長時最深處就已經分離出原型地核,則地函中這些區塊擁有的化學性質可以解釋現今觀察到鎢和氙同位素呈現的特殊訊號,代表直到今日這些區塊和地函其他區域始終沒有完全混和。
據Bennett所言:「我們發現碘具有一種重要性質,它在相當高的溫度和壓力之下會開始溶入地核當中。在此極端環境下,碘和鉿(一種會放射性衰變成氙和鎢的元素)對形成地核的金屬會呈現出相反的喜好。這種行為造成的特殊同位素訊號跟我們現今在熱點看到的如出一轍。」
團隊的計算結果也預測鎢和氙的同位素訊號應該跟地函內部密度較高的區塊有關。
「就像是做餅乾的麵糰中加入的巧克力脆片,地函中這些密度較高的區塊非常難以攪拌開來。對於它們蘊含的古老鎢和氙同位素訊號來說,或許這是它們可以保存至今日的重要因素之一。」Jackson解釋。
「讓人更加興奮的是有越來越多地球物理證據顯示,緊鄰在地核上方的地函事實上有些密度較高的區域,它們被稱為超低速帶(ultralow velocity zones)或是大型低剪力波速群(large low shear velocity provinces)。而我們的研究成果和這些觀察可以緊密結合。」Fei補充,「我們在此研究中發展的方法也讓我們擁有新的機會能夠直接研究在地球深處發生的作用。」
本研究由國家科學基金會、卡內基科學研究院以及史密森尼學會資助。

Earth's core and mantle separated in a disorderly fashion
Plumes of hot rock surging upward from the Earth's mantle at volcanic hotspots contain evidence that the Earth's formative years may have been even more chaotic than previously thought, according to new work from a team of Carnegie and Smithsonian scientists published in Nature.
It is well understood that Earth formed from the accretion of matter surrounding the young Sun. Eventually the planet grew to such a size that denser iron metal sank inward, to form the beginnings of the Earth's core, leaving the silicate-rich mantle floating above.
But new work from a team led by Carnegie's Yingwei Fei and Carnegie and the Smithsonian's Colin Jackson argues that this mantle and core separation was not such an orderly process.
"Our findings suggest that as the core was extracted from the mantle, the mantle never fully mixed," Jackson explained. "This is surprising because core formation happened in the immediate wake of large impacts from other early Solar System objects that Earth experienced during its growth, similar to the giant impact event that later formed the Moon. Before now, it was widely thought that these very energetic impacts would have completely stirred the mantle, mixing all of its components into a uniform state."
The smoking gun that led the team to their hypothesis comes from unique and ancient tungsten and xenon isotopic signatures found at volcanic hotspots, such as Hawaii. Although it was believed that these plumes originated from the mantle's deepest regions, the origin of these unique isotopic signatures has been debated. The team believes that the answer lies in the chemical behavior of iodine, the parent element of xenon, at very high pressure.
Isotopes are versions of elements with the same number of protons, but different numbers of neutrons. Radioactive isotope of elements, such as iodine-129, are unstable. To gain stability, iodine-129 decays into xenon-129. Therefore, the xenon isotopic signatures in plume mantle samples are directly related to iodine's behavior during the period of core-mantle separation.
Using diamond anvil cells to recreate the extreme conditions under which Earth's core separated from its mantle, Jackson, Fei, and their colleagues -- Carnegie's Neil Bennett and Zhixue Du and Smithsonian's Elizabeth Cottrell -- determined how iodine was partitioning between metallic core and silicate mantle. They also demonstrated that if the nascent core separated from the deepest regions of the mantle while it was still growing, then these pockets of the mantle would possess the chemistry needed to explain the unique tungsten and xenon isotopic signatures, provided these pockets remained unmixed with the rest of the mantle all the way up through the present day.
According to Bennett: "The key behavior we identified was that iodine starts to dissolve into the core under very high pressures and temperatures. At these extreme conditions, iodine and hafnium, which decay radioactively to xenon and tungsten, display opposing preferences for core-forming metal. This behavior would lead to the same unique isotopic signatures now associated with hotspots."
Calculations from the team also predict that the tungsten and xenon isotopic signatures should be associated with dense pockets of the mantle.
"Like chocolate chips in cookie batter, these dense pockets of the mantle would be very difficult stir back in, and this may be a crucial aspect to the retention of their ancient tungsten and xenon isotopic signatures to the modern day," Jackson explained.
"Even more exciting is that there is increasing geophysical evidence that there actually are dense regions of mantle, resting just above the core -- called ultralow velocity zones and large low shear velocity provinces. This work ties together these observations," Fei added. "The methodology developed here also opens new opportunities for directly studying the deep Earth processes."
This work was supported by the National Science Foundation, the Carnegie Institution for Science, and the Smithsonian Institution.
原始論文:Colin R. M. Jackson, Neil R. Bennett, Zhixue Du, Elizabeth Cottrell & Yingwei Fei. Early episodes of high-pressure core formation preserved in plume mantle. Nature, 2018 DOI: 10.1038/nature25446

引用自:Carnegie Institution for Science. "Earth's core and mantle separated in a disorderly fashion."

2017年4月25日 星期二

年輕的火山岩中有遠古地球留下的記號

原文網址:www.sciencedaily.com/releases/2017/04/170406143910.htm
年輕的火山岩中有遠古地球留下的記號
地球化學傳遞出的線索顯示夏威夷和薩摩亞的某些岩石,可能具有地球甫誕生時就形成的物質。
組成地球地函的岩石雖然堅硬但也會在數百萬年之間緩緩流動。某些地質學家推測這種緩慢循環會完全抹滅產生自地球歷史早期的地球化學痕跡。但馬里蘭大學的地質學家領導的新研究中,發現的新證據卻可以追溯至超過45億年前。